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Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Discrete spherical hexadecavanadates incorporating a bromide with oxidative bromination activity

Naohiro Kato1, Yoshihito Hayashi

  • 1Department of Chemistry, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma, Kanazawa, 920-1192, Japan.

Dalton Transactions (Cambridge, England : 2003)
|July 17, 2013
PubMed
Summary

Researchers synthesized two novel hexadecavanadates, spherical clusters containing chloride or bromide. These mixed-valence vanadium-oxygen frameworks exhibit unique redox properties and catalytic activity in oxidative bromination reactions.

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