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Capillary deformations of bendable films.

R D Schroll1, M Adda-Bedia, E Cerda

  • 1Physics Department, University of Massachusetts, Amherst, Massachusetts 01003, USA.

Physical Review Letters
|July 19, 2013
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We found that liquid drops on ultrathin, bendable solid sheets exhibit a modified contact angle due to elastocapillary effects. Wrinkle pattern size is predictable, enabling precise measurements of thin films.

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Area of Science:

  • Physics
  • Materials Science
  • Surface Science

Background:

  • Classical theories describe liquid drop contact angles on solid surfaces.
  • Ultrathin solid sheets on deformable foundations present unique wetting behaviors.

Purpose of the Study:

  • To investigate the partial wetting of liquid drops on ultrathin solid sheets.
  • To understand the elastocapillary phenomena governing liquid-solid-vapor interactions on highly bendable sheets.
  • To develop a predictable model for wrinkle patterns in such systems.

Main Methods:

  • Theoretical calculations based on membrane theory.
  • Experimental validation of theoretical predictions.
  • Analysis of liquid-solid-vapor contact angle modification.

Main Results:

  • The liquid-solid-vapor contact angle deviates from the Young angle due to sheet bendability, not material softness.
  • A new elastocapillary phenomenon driven by high bendability was identified.
  • The size of emergent wrinkle patterns is fully predictable.

Conclusions:

  • High bendability of ultrathin sheets introduces a novel elastocapillary effect impacting wetting.
  • Predictable wrinkle patterns allow for quantitative, calibration-free metrology of ultrathin films.
  • This work revises classical wetting theories for highly deformable thin films.