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Updated: May 9, 2026

Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
Published on: May 12, 2023
A crown-shaped 24-molybdate cluster constructed by organotriphosphonate ligand
Lu Yang1, Pengtao Ma, Zhen Zhou
1Henan Key Laboratory of Polyoxometalate Chemistry, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University Kaifeng, Henan 475004, People's Republic of China.
Abstract:
A crown-shaped organic-inorganic hybrid polyoxomolybdate, Na5[H7{N(CH2PO3)3}Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclearity of metal atoms in the area of organophosphonate-based polyoxometalates.
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