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Modified boron subphthalocyanines with stable electrochemistry and tuneable bandgaps
Brett A Kamino1, Timothy P Bender
1Department of Chemical Engineering and Applied Chemistry, 200 College St., Toronto, Ontario, CanadaM5S3E5.
Abstract:
The synthesis of boron subphthalocyanines (BsubPc) from modified phthalonitriles is reported. The BsubPcs have intense red-shifted absorption compared to normal BsubPcs and readily tuneable optoelectronic properties including enhanced electrochemical stability and the presence of up to two reversible electrochemical reductions.
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