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Molecular flexibility and structural instabilities in crystalline l-methionine

Jennifer Fischer1, José A Lima, Paulo T C Freire

  • 1Institute of Physics and Center for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Heinrich-Plett-Str. 40, 34132 Kassel, Germany; Helmholtz Zentrum Berlin für Materialien und Energie, Hahn Meitner Platz 1, 14109 Berlin, Germany.

Biophysical Chemistry
|July 27, 2013
PubMed
Summary

Crystalline l-methionine exhibits dynamic disorder above 275K, linked to its flexible thiol-ether group. This structural transition involves changes in lattice parameters and molecular motions, studied via neutron scattering and X-ray diffraction.

Keywords:
Amino acidComputationDynamicsFlexibilitySpectroscopyStructure

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