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Rh(II)-catalyzed reactions of differentially substituted bis(diazo) functionalities

Sara A Bonderoff1, Albert Padwa

  • 1Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.

Organic Letters
|July 30, 2013
PubMed
Summary

Donor/acceptor diazo groups in molecules undergo selective reactions like cyclopropanation, leaving acceptor/acceptor diazo groups for further reactions. This rhodium(II)-catalyzed process enables sequential chemical transformations.

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