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Synthesis, Characterization, and Functionalization of Hybrid Au/CdS and Au/ZnS Core/Shell Nanoparticles
Published on: March 2, 2016
Poly[μ₇-sulfanediyldiacetato-disilver(I)]
Xiao-Min Hao1, Gang Chen, Chang-Sheng Gu
1Department of Chemistry, Harbin Institute of Technology, Harbin 150001, People's Republic of China.
Abstract:
In the title coordination polymer, [Ag₂(C₄H₄O₄S)], each AgI cation is four-coordinated by three of the four carboxylate O atoms and the S atom from symmetry-related sulfanediyldiacetate ligands, thus defining a distorted tetrahedral geometry at the metal centre. The AgI cations are bridged by sulfanediyldiacetate groups, leading to a two-dimensional layer structure. These layers are interconnected via Ag-S bonds to form a three-dimensional coordination polymer network overall.
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