Related Experiment Video
Updated: May 9, 2026

Atomic Layer Deposition of Vanadium Dioxide and a Temperature-dependent Optical Model
Published on: May 23, 2018
Description of van der Waals interactions using transformation optics.
Rongkuo Zhao1, Yu Luo, A I Fernández-Domínguez
1The Blackett Laboratory, Department of Physics, Imperial College London, London SW7 2AZ, United Kingdom. r.zhao@imperial.ac.uk
Calculating van der Waals forces between plasmonic nanoparticles is difficult. Transformation optics provides a new way to understand electromagnetic fields in tiny gaps, yielding universal formulas for these interactions.
Area of Science:
- Condensed matter physics
- Plasmonics
- Nanotechnology
Background:
- Calculating van der Waals interactions in closely spaced plasmonic nanoparticles is complex.
- Strong electromagnetic field concentration occurs in the nanometric gap, posing a challenge.
Purpose of the Study:
- To provide a theoretical framework for understanding van der Waals interactions between plasmonic nanoparticles.
- To develop universal analytical expressions for these interactions.
Main Methods:
- Utilizing the technique of transformation optics.
- Mapping small volumes to desired length scales to analyze electromagnetic fields.
- Deriving analytical expressions for van der Waals forces.
Main Results:
- Obtained universal analytical expressions for van der Waals interactions.
- Demonstrated the utility of transformation optics for analyzing nanoscale electromagnetic phenomena.
- Provided physical insight into electromagnetic field behavior in nanometric gaps.
Conclusions:
- Transformation optics offers a powerful tool for studying van der Waals forces in plasmonic systems.
- The derived expressions are applicable to spherical nanoparticles made of realistic metals at various separations.
Related Concept Videos
Van der Waals Interactions
Van der Waals Equation
First, the attractive forces between molecules, which are stronger at higher densities and reduce the pressure, are considered by adding to the pressure a term equal to the square of the molar density multiplied by a positive coefficient a. Second, the volume...
The Van der Waals Equation
The de Broglie Wavelength
Real Gases: Effects of Intermolecular Forces and Molecular Volume Deriving Van der Waals Equation
Vector Transformation in Rotating Coordinate Systems
