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Nonporous titanium-oxo molecular clusters that reversibly and selectively adsorb carbon dioxide
1Department of Applied Chemistry, College of Science and Technology, Hanyang University, 55 Hanyangdaehak-ro, Ansan 426-791, Republic of Korea.
Abstract:
Nonporous titanium(IV) clusters supported by carboxylate ligands show selective sorption of carbon dioxide even in the amorphous phase. A ring-type Ti8 cluster with a permanent inner pore also adsorbs gases, but not selectively.
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