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Seeded Synthesis of CdSe/CdS Rod and Tetrapod Nanocrystals
Published on: December 11, 2013
Anisotropy of optical transitions in ordered ensemble of CdSe quantum rods
Maria V Mukhina1, Vladimir G Maslov, Alexander V Baranov
1Saint Petersburg National Research University of Information Technologies, Mechanics and Optics, Saint Petersburg, Russia.
Abstract:
We report on the observation of spectral dependence of absorption anisotropy in a CdSe quantum rod (QR) ensemble, which is aligned in a polymer film with a nanocrystal concentration of 2×10(-5) M. The experimental data on the polarization direction and anisotropy factor were obtained for the lowest excitonic transition and the second group of transitions in the QR. The nonzero constant value of anisotropy was investigated for the high-energy transitions, and is evidence of the one-dimensional confinement in the QR.
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