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Updated: May 8, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Fluorinated and trifluoromethylated corannulenes

Bernd M Schmidt1, Berit Topolinski, Mihoko Yamada

  • 1Freie Universität Berlin, Institut für Chemie und Biochemie, Fabeckstrasse 34-36, 14195 Berlin (Germany); Institute for Molecular Science, Myodaiji, Okazaki 444-8787 (Japan).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|September 7, 2013
PubMed
Summary

This study reports the synthesis of corannulenes with electron-withdrawing groups like fluorine and trifluoromethyl. These novel compounds were characterized, revealing their unique molecular structures and electron-acceptor properties.

Keywords:
corannuleneselectrochemistryfluorinestacking interactionstrifluoromethylation

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