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Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles
Published on: November 27, 2015
Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(IV)-Ni(II) molecular
Dao-Peng Zhang1, Li-Fang Zhang, Guo-Ling Li
1School of Chemical Engineering and Technology, China University of Mining and Technology, XuZhou 221116, P. R. China. nizhonghaicumt@gmail.com.
Chemical Communications (Cambridge, England)
|September 11, 2013
Abstract:
One cyanide-bridged W(IV)-Ni(II) wheel-like complex and two three-dimensional (3D) networks can be directly synthesized based on K4[W(CN)8] and [Ni(L)](ClO4)2 precursors by controlling the quantity of water in organic solvent. The water-controlled single-crystal structural transformations among these complexes are described.
