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Unprecedented activation and CO2 capture properties of an elastic single-molecule trap
Mario Wriedt1, Julian P Sculley, Wolfgang M Verdegaal
1Department of Chemistry & Biomolecular Science, Clarkson University, Potsdam, NY 13699-5810, USA. mwriedt@clarkson.edu.
Chemical Communications (Cambridge, England)
|September 12, 2013
Abstract:
The activation and CO2 capture properties of a microporous metal-organic framework with elastic single-molecule traps were systematically investigated. This material shows a unique low-energy gas-purge activation capability, high CO2 adsorption selectivities over various gases and optimized working capacities per energy of 2.9 mmol kJ(-1) at 128 °C.
