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Related Experiment Video

Updated: Jun 6, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

Reprogramming Porosity: The Synthetic Evolution of Pore Engineering in Metal-Organic Frameworks.

Ankit Mondal1, Kelechi Festus1,2, Prapassara Muangsopa1

  • 1Department of Chemistry, Texas A&M University, College Station, Texas 77843, United States.

ACS Materials Letters
|June 5, 2026
PubMed
Summary
This summary is machine-generated.

Metal-organic frameworks (MOFs) offer tunable porosity through synthetic pore reprogramming. This approach allows systematic modification of MOFs for advanced material design and tailored performance.

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Determining Surface Areas and Pore Volumes of Metal-Organic Frameworks
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Determining Surface Areas and Pore Volumes of Metal-Organic Frameworks

Published on: March 8, 2024

Area of Science:

  • Materials Science
  • Chemistry

Background:

  • Metal-organic frameworks (MOFs) are crystalline porous materials with tunable properties.
  • Traditional pore engineering relied on linker length and metal node choice.
  • Recent advances allow active reprogramming of MOF pore environments.

Purpose of the Study:

  • To review strategies for tuning MOF pore characteristics.
  • To unify these strategies under the concept of synthetic pore reprogramming.
  • To establish design rules for MOF modification while maintaining structural integrity.

Main Methods:

  • Discusses linker exchange, insertion, and defect engineering.
  • Highlights cluster metalation and postsynthetic modifications (covalent/coordinative).
  • Covers the growth of functional species within MOF pores.

Main Results:

  • Identifies mechanistic design rules for MOF transformations.
  • Demonstrates systematic modification of MOFs beyond their original structures.
  • Enables access to novel properties and functions.

Conclusions:

  • Synthetic pore reprogramming provides a framework for designing programmable MOFs.
  • This approach allows for tailored performance unattainable in pristine MOFs.
  • Lays the foundation for advanced functional porous materials.