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Updated: May 7, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Synthesis, characterisation, and oxygen atom transfer reactions involving the first gold(I)-alkylperoxo complexes
Alba Collado1, Adrián Gómez-Suárez, Yoshihiro Oonishi
1EaStCHEM School of Chemistry, University of St. Andrews, St. Andrews, KY16 9ST, UK. snolan@st-andrews.ac.uk.
Abstract:
The synthesis of a new class of organogold species containing a peroxo moiety is reported. Complexes [Au(IPr)(OO(t)Bu)] and [Au(SIPr)(OO(t)Bu)] have been synthesised via a straightforward methodology using the parent gold(I) hydroxide complexes as synthons. These complexes have been successfully used in oxygen-transfer reactions to triphenylphosphine.
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