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Vibrational energy flow between modes by dynamic mode coupling in THIATS J-aggregates

Daisuke Hasegawa1, Kazuaki Nakata, Eiji Tokunaga

  • 1Department of Physics, Faculty of Science, Tokyo University of Science , 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan.

The Journal of Physical Chemistry. A
|October 12, 2013
PubMed
Summary

Ultrafast spectroscopy revealed excited molecular vibrations in THIATS cyanine dye J-aggregates. Energy flows to a 1633 cm(-1) mode, with excited state lifetimes of 52 fs and 540 fs determined.

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