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Updated: May 6, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
Published on: April 10, 2015
Half-sandwich arene ruthenium complexes: synthetic strategies and relevance in catalysis
Prashant Kumar1, Rakesh Kumar Gupta, Daya Shankar Pandey
1Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi - 221 005 (U.P.), India. dspbhu@bhu.ac.in.
Abstract:
Half-sandwich arene ruthenium complexes exhibit versatile chemistry, serve as excellent precursors and find potential applications in many organic transformations. This review mainly focuses on the chemistry of piano-stool ruthenium complexes with special emphasis on the achiral or chiral-at-ruthenium center. Also, it deals with the synthesis, nomenclature and stereochemistry of arene ruthenium complexes along with mechanistic insights into the epimerization reactions and their applications in catalytic organic transformations with some selected examples.
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