AIE-Active BODIHYs Based on Benzothiazole-Hydrazone Chelates and Their Artificial Light Harvesting and Reversible Mechanochromic Behavior
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Updated: Sep 16, 2025

Determination of the Photoisomerization Quantum Yield of a Hydrazone Photoswitch
Published on: February 7, 2022
Nikhil Kumar Singh1, Ashish Kumar Kushwaha1, Daya Shankar Pandey1
1Department of Chemistry, Institute of Science, Banaras Hindu University, Varanasi, Uttar Pradesh, 221005, India.
Abstract:
Efficient artificial light-harvesting systems (ALH) involving energy transfer via FRET in an aqueous environment has been reported. Hydrazone ligands L1-L3 and -BF2 complexes (BODIHYs; B1-B3) derived from these have been synthesized and meticulously characterized by various techniques like1H, 13C, 11B, 19F NMR, ESI-MS, UV-vis, fluorescence spectroscopy, and structures of B1 and B2 unequivocally determined by X-ray single crystal analyses. Applicability of the B1-B3 have been examined as a LHS platform and categorically shown that these in combination with rhodamine B (RhB) display efficient light harvesting activity under aqueous conditions via aggregation-induced emission (AIE). Calculated energy transfer efficiency and antenna effect for the BODIHYs are significantly high (B1 = 22%, 5.04; B2 = 18%, 4.07) at a donor/acceptor ratio of 23:1. Furthermore, hypsochromic shift shown by B1 and B2 after grinding completely reverses upon exposure to dichloromethane vapors. Powder X-ray diffraction (PXRD) analyses before and after grinding revealed that the external forces modify crystal packing by disrupting weak intra- and intermolecular interactions within the molecules.
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