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Ionization-induced π → H site-switching in phenol-CH4 complexes studied using IR dip spectroscopy

Mitsuhiko Miyazaki1, Akihiro Takeda, Matthias Schmies

  • 1Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503, Japan. mfujii@res.titech.ac.jp.

Physical Chemistry Chemical Physics : PCCP
|November 15, 2013
PubMed
Summary

Photoionization of phenol-methane complexes reveals a shift from pi-bound to hydrogen-bonded structures. This ionization-induced structural change occurs with high efficiency in methane complexes due to vibrational energy redistribution.

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