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Liquid–Solid Solutions

Liquid–Solid Solutions

The process of a solid dissolving in a liquid to form a solution is governed by the solubility limit, which is the maximum amount of the solid substance, or solute, that can be dissolved in a specific volume of the liquid or solvent. As the solute dissolves, it reaches a point where no more solute can be dissolved at a given temperature - this is known as the saturation point. However, if further solute is added and it manages to dissolve, the solution becomes supersaturated. Supersaturated...

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Updated: May 5, 2026

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Aqueous Droplets Used as Enzymatic Microreactors and Their Electromagnetic Actuation

Published on: August 28, 2017

Robust liquid marbles stabilized with surface-modified halloysite nanotubes.

Hui Wu¹, Hirohmi Watanabe, Wei Ma

¹ERATO Takahara Soft Interface Project, Japan Science and Technology Agency (JST) , 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan.

Langmuir : the ACS Journal of Surfaces and Colloids

|November 22, 2013

Summary

Researchers created strong, fluorine-free liquid marbles using modified halloysite nanotubes. This nature-inspired approach avoids harmful chemicals, offering a sustainable alternative for advanced material design.

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Last Updated: May 5, 2026

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Facile Preparation of Internally Self-assembled Lipid Particles Stabilized by Carbon Nanotubes

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Published on: February 19, 2016

Area of Science:

Materials Science
Nanotechnology
Surface Chemistry

Background:

Liquid marbles offer unique properties but often rely on fluorinated materials.
Developing fluorine-free alternatives is crucial for environmental and safety reasons.
Halloysite nanotubes are abundant, naturally occurring inorganic materials.

Purpose of the Study:

To fabricate robust, fluorine-free liquid marbles.
To explore the use of surface-modified halloysite nanotubes as a coating material.
To mimic natural superhydrophobic surfaces for enhanced material properties.

Main Methods:

Surface modification of halloysite nanotubes with octadecyltrimethoxysilane.
Fabrication of liquid marbles using the modified nanotubes.
Characterization of the liquid marbles' surface properties and mechanical strength.

Main Results:

Successfully created fluorine-free liquid marbles with high mechanical strength.
Surface-modified halloysite nanotubes formed effective superhydrophobic coatings.
The resulting liquid marbles exhibited properties comparable to natural superhydrophobic surfaces.

Conclusions:

Halloysite nanotubes provide a viable, eco-friendly alternative for liquid marble fabrication.
Surface modification is key to achieving superhydrophobicity and mechanical robustness.
This study presents a novel, nature-inspired strategy for designing advanced liquid marble materials.