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Direct grafting of poly(pentafluorophenyl acrylate) onto oxides: versatile substrates for reactive microcapillary
Rachelle M Arnold1, Christopher D McNitt, Vladimir V Popik
1Department of Chemistry, College of Engineering, and the Center for Nanoscale Science and Engineering, University of Georgia, Athens, GA 30602, USA. jlocklin@uga.edu.
Chemical Communications (Cambridge, England)
|November 26, 2013
Abstract:
Poly(pentafluorophenyl acrylate) was covalently attached to silicon oxide through the direct coupling of the reactive ester to surface silanol groups. Subsequently, reactive microcapillary printing (R-μCaP) and a one-pot, self-sorting postpolymerization modification reaction were used to generate patterns of spatially resolved chemical functionality.
