Supercontinuum spatial modulation spectroscopy: detection and noise limitations

Supercontinuum spatial modulation spectroscopy is a facile tool for conducting single molecule/particle extinction spectroscopy throughout the visible and near infrared (420-1100 nm). The technique's capabilities are benchmarked using individual Au nanoparticles (NPs) as a standard since they are well studied and display a prominent plasmon resonance in the visible. Extinction spectra of individual Au NPs with diameters (d) ranging from d ~ 8 to 40 nm are resolved with extinction cross sections (σ(ext)) of σ(ext) ~ 1 × 10(-13)-1 × 10(-11) cm(2). Corresponding signal-to-noise ratios range from ~30 to ~1400. The technique's limit of detection is determined to be 4.3 × 10(-14) cm(2) (4.3 nm(2)). To showcase supercontinuum spatial modulation spectroscopy's broader applicability, extinction spectra are acquired for other model systems, such as individual single-walled carbon nanotubes (SWCNTs) and CdSe nanowires. We show for the first time extinction spectra of individual (8,3) and (6,5) SWCNTs. For both chiralities, their E11 [(8,3) 1.30 eV (952 nm); (6,5) 1.26 eV (986 nm)] and E22 [(8,3) 1.86 eV (667 nm); (6,5) 2.19 eV (567 nm)] excitonic resonances are seen with corresponding cross sections of σ(ext) ~ 10(-13) cm(2) μm(-1).