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X-ray structure of a porphyrin-tetramethylcucurbit[6]uril supramolecular polymer

Xin Xiao1, Junshan Sun, Jianzhuang Jiang

  • 1Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing 100083 (China), Fax: (+86) 10-6233-2462; Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Department of Chemistry, Guizhou University, Guiyang 550025 (China).

Chemistry (Weinheim an Der Bergstrasse, Germany)
|December 6, 2013
PubMed
Abstract

No abstract available in PubMed .

Keywords:
cucurbit[n]urilhost-guest systemporphyrinself-assemblysupramolecular polymer

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Cycloheptatriene is a neutral monocyclic unsaturated hydrocarbon that consists of an odd number of carbon atoms and an intervening sp3 carbon in the ring. The three double bonds in the ring correspond to 6 π electrons, which is a Huckel number, and therefore satisfies the criteria of 4n + 2 π electrons. However, the intervening sp3 carbon disrupts the continuous overlap of p orbitals. As a result, cycloheptatriene is not aromatic.
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