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Updated: May 4, 2026

Digital Printing of Titanium Dioxide for Dye Sensitized Solar Cells
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Highly efficient plastic crystal ionic conductors for solid-state dye-sensitized solar cells.

Daesub Hwang1, Dong Young Kim2, Seong Mu Jo2

  • 11] Department of Chemistry, Yonsei University, Seoul 120-749, Korea [2] Optoelectronic Materials Lab, Korea Institute of Science and Technology, Seoul 136-791, Korea.

Scientific Reports
|December 18, 2013
PubMed
Summary
This summary is machine-generated.

Highly efficient solid-state ionic conductors were developed for dye-sensitized solar cells (DSSCs) using a plastic crystal, succinonitrile. These novel materials achieve high performance, offering a promising strategy for advanced electrochemical devices.

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Area of Science:

  • Materials Science
  • Electrochemistry
  • Renewable Energy

Background:

  • Dye-sensitized solar cells (DSSCs) are a promising photovoltaic technology.
  • Development of efficient solid-state electrolytes is crucial for advancing DSSC performance and stability.
  • Existing ionic liquid electrolytes face challenges in terms of volatility and cost.

Purpose of the Study:

  • To develop highly efficient, ambient temperature, solid-state ionic conductors (SSICs) for DSSCs.
  • To investigate the use of doped molecular plastic crystals as a novel electrolyte material.
  • To achieve high power conversion efficiency in solid-state DSSCs.

Main Methods:

  • Doping succinonitrile (SN), a molecular plastic crystal, with trialkyl-substituted imidazolium iodide salts.
  • Fabrication of solid-state DSSCs utilizing the developed SSICs.
  • Integration of SSICs with unique hierarchically nanostructured TiO₂ sphere (TiO₂-SP) photoelectrodes with enhanced macroporosity.

Main Results:

  • Achieved high ionic conductivity in the SSICs, ranging from 2-4 mScm⁻¹.
  • Fabricated high-performance solid-state DSSCs with a power conversion efficiency of 7.8%.
  • Demonstrated superior performance compared to previous plastic crystal-based SSICs and comparable performance to state-of-the-art ionic liquid electrolytes.

Conclusions:

  • Developed efficient plastic crystal-based SSICs for solid-state DSSCs.
  • Hierarchically nanostructured TiO₂-SP photoelectrodes facilitate solid electrolyte penetration, enhancing device performance.
  • This strategy offers a viable pathway for developing efficient SSICs for DSSCs and other electrochemical applications.