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Updated: May 4, 2026

Atom Transfer Radical Polymerization of Functionalized Vinyl Monomers Using Perylene as a Visible Light Photocatalyst
Published on: April 22, 2016
Ambient temperature catalyst-free light-induced preparation of macrocyclic aliphatic polyesters
Thomas Josse1, Ozcan Altintas, Kim K Oehlenschlaeger
1Center of Innovation and Research in Materials and Polymers (CIRMAP), Laboratory of Polymeric and Composite Materials, University of Mons, 23 Place du Parc, B-7000, Mons, Belgium. olivier.coulembier@umons.ac.be.
Abstract:
The light induced, catalyst-free ambient temperature preparation of macrocyclic aliphatic polyesters is pioneered. Based on the photo-induced Diels-Alder reaction of orthoquinodimethane and acrylate moieties, cyclic polyesters of high purity are readily synthesized. Considering the high tolerance to functional groups and the orthogonality of the ligation, the reported protocol can be easily transferred to a large range of polymers, complex topologies (tadpole, sun-shaped, jellyfish, etc.) and applications.
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