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Updated: May 4, 2026

Facile Preparation of 2Z,4E-Dienamides by the Olefination of Electron-deficient Alkenes with Allyl Acetate
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Enantio- and regioselective iridium-catalyzed allylic esterification.

Jianping Qu1, Lydia Roßberg, Günter Helmchen

  • 1Organisch-Chemisches Institut der Ruprecht-Karls-Universität Heidelberg, Im Neuenheimer Feld 270, D-69120 Heidelberg, Germany.

Journal of the American Chemical Society
|January 16, 2014
PubMed
Summary

This study presents a new iridium-catalyzed reaction for synthesizing branched allylic esters with high selectivity. The method directly converts carboxylates and allylic phosphates, sometimes including kinetic resolution for enhanced enantiomeric excess.

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