Related Experiment Video
Updated: May 3, 2026

Fabrication of Gate-tunable Graphene Devices for Scanning Tunneling Microscopy Studies with Coulomb Impurities
Published on: July 24, 2015
Observation of a universal donor-dependent vibrational mode in graphene
A V Fedorov1, N I Verbitskiy2, D Haberer3
11] IFW Dresden, P.O. Box 270116, Dresden D-01171, Germany [2] St Petersburg State University, Ulianovskaya 1, St Petersburg 198504, Russia.
Abstract:
Electron-phonon coupling and the emergence of superconductivity in intercalated graphite have been studied extensively. Yet, phonon-mediated superconductivity has never been observed in the 2D equivalent of these materials, doped monolayer graphene. Here we perform angle-resolved photoemission spectroscopy to try to find an electron donor for graphene that is capable of inducing strong electron-phonon coupling and superconductivity. We examine the electron donor species Cs, Rb, K, Na, Li, Ca and for each we determine the full electronic band structure, the Eliashberg function and the superconducting critical temperature Tc from the spectral function. An unexpected low-energy peak appears for all dopants with an energy and intensity that depend on the dopant atom. We show that this peak is the result of a dopant-related vibration. The low energy and high intensity of this peak are crucially important for achieving superconductivity, with Ca being the most promising candidate for realizing superconductivity in graphene.
Related Concept Videos
IR Spectrum Peak Splitting: Symmetric vs Asymmetric Vibrations
IR Spectroscopy: Molecular Vibration Overview
Stretching vibrations are vibrational motions that occur along the bond line, changing the bond length or distance between two bonded atoms. They are further distinguished as symmetric or asymmetric. In symmetric stretching, the...
IR Spectroscopy: Hooke's Law Approximation of Molecular Vibration
According to Hooke's law, the vibrational frequency is directly proportional to...
IR and UV–Vis Spectroscopy of Aldehydes and Ketones
UV–Vis Spectroscopy: Molecular Electronic Transitions
IR Absorption Frequency: Delocalization
In IR...

