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Patterned surface with controllable wettability for inkjet printing of flexible printed electronics
Phuong Q M Nguyen1, Lip-Pin Yeo, Boon-Keng Lok
1School of Mechanical and Aerospace Engineering, Nanyang Technological University , 50 Nanyang Avenue, Singapore 639798.
ACS Applied Materials & Interfaces
|February 28, 2014
Summary
Researchers developed novel patterned surfaces with both hydrophilic and hydrophobic properties. This surface engineering enables precise inkjet printing of fine conductive features, improving resolution and print quality.
Area of Science:
- Materials Science
- Surface Engineering
- Nanotechnology
Background:
- Inkjet printing is a versatile technique for fabricating electronic devices.
- Achieving high-resolution printing of conductive inks requires precise control over substrate surface properties.
- Existing methods often struggle with controlling wettability for complex patterns.
Purpose of the Study:
- To investigate novel methods for creating patterned surfaces with combined hydrophilic and hydrophobic properties.
- To demonstrate the effectiveness of these patterned surfaces for high-resolution inkjet printing.
- To improve the printing quality of fine resolution structures using controlled surface wettability.
Main Methods:
- Fabrication of patterned surfaces using a two-step coating process with 3-aminopropyl trimethoxysilane (APTMS) and a 3M electronic grade chemical on PET surfaces.
- Selective hydrophilic treatment of specific regions using atmospheric O2/Ar plasma or UV/ozone treatment with a Nickel stencil.
- Characterization of surface wettability using water contact angle (WCA) measurements.
- Inkjet printing of PEDOT/PSS conductive ink on the patterned surfaces.
Main Results:
- Creation of surfaces with distinct hydrophobic regions (WCA ~105°) and superhydrophilic regions (WCA <5°).
- Selective wetting of PEDOT/PSS conductive ink, with ink spreading along hydrophilic areas and avoiding hydrophobic regions.
- Successful inkjet printing of fine features smaller than the droplet size (~55 μm) due to high wettability contrast.
Conclusions:
- Controlled surface wettability is crucial for improving inkjet printing resolution and quality.
- The developed two-step coating and selective treatment method effectively creates patterned surfaces for precise ink deposition.
- This approach offers a viable strategy for fabricating microscale conductive patterns using inkjet printing.

