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Computationally Efficient Steady-State Solution of the Bloch Equations for Rapid Sinusoidal Scans Based on Fourier
Mark Tseitlin1, Gareth R Eaton1, Sandra S Eaton1
1Department of Chemistry and Biochemistry, University of Denver, Denver, CO 80208.
Abstract:
Rapid-scan EPR has been shown to improve the signal-to-noise ratio relative to conventional continuous wave spectroscopy. Equations are derived for the steady-state solution to the Bloch equations as a Fourier expansion in the harmonics of the scan frequency. This simulation method is about two orders of magnitude faster than time-domain numerical integration.
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