4-Pyridyl-substituted azacycloalkanes with multiple donor sites prepared via a solvent-free, one-pot method for use
B K Breedlove1, R Kandel, H Md Ahsan
1Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki Aza Aoba, Sendai, 980-8578, Japan. breedlove@m.tohoku.ac.jp.
Abstract:
We report the first, solvent-free synthesis of 4-pyridyl tacn, cyclen, and cyclam derivatives as new design elements to prepare electrocatalysts, for example, by the differential metal complexation of 4-py(n)cyclen (n = 2, 4).
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