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Updated: Apr 30, 2026

Self-assembling Morphologies Obtained from Helical Polycarbodiimide Copolymers and Their Triazole Derivatives
Published on: February 7, 2017
Intramolecular folding of triblock copolymers via quadrupole interactions between poly(styrene) and
Jie Lu1, Niels Ten Brummelhuis, Marcus Weck
1Molecular Design Institute, Department of Chemistry, New York University, New York, NY 10003, USA. marcus.weck@nyu.edu.
Abstract:
β-Hairpin formation is one of the fundamental folding actions in biomacromolecules. We present a linear triblock copolymer synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization, that is able to mimic on a very basic level hairpin formation by using π-π stacking interactions between phenyl and 2,3,4,5,6-pentafluorophenyl residues.
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