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Multiscale Sampling of a Heterogeneous Water/Metal Catalyst Interface using Density Functional Theory and Force-Field Molecular Dynamics
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Ethanol oxidation on Pt single-crystal electrodes: surface-structure effects in alkaline medium.

Carlos Busó-Rogero1, Enrique Herrero, Juan M Feliu

  • 1Instituto de Electroquímica, Universidad de Alicante, Apdo. 99, E-03080, Alicante (Spain), Fax: (+34) 965903537.

Chemphyschem : a European Journal of Chemical Physics and Physical Chemistry
|May 1, 2014
PubMed
Summary

Ethanol oxidation on platinum electrodes in alkaline solution shows reversed activity compared to acidic media. Electrode deactivation is linked to acetaldehyde formation and adsorption.

Keywords:
IR spectroscopyalkaline solutionsoxidationplatinumsingle-crystal electrodes

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