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Published on: August 10, 2017
Separation-dependence evolution of inter-particle interaction in the oriented-attachment growth of nanorods: a case
Yuanqiang Song1, Aifang Liu, Yu Pan
1School of Energy Science and Engineering, University of Electronic Science and Technology of China (UESTC), Chengdu, 611731, PR China.
Abstract:
Previous reports only evaluated the correlation between oriented-attachment growth and part of the interaction, i.e., either van der Waals interaction or Coulombic interaction. By focusing on hexagonal nanorods, a relatively complex form of 1D nanocrystals, this article takes into account both dominant interactions and systematically investigates their countering effects on the separation dependence of the inter-particle interaction in the oriented-attachment growth of 1D nanocrystals. As elucidated by the Arrhenius equation, the growth kinetics and thermodynamics of oriented-attachment nanocrystals can thus be evaluated with such quantitatively resolved inter-particle interactions between the attaching objects.
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