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Stereospecific cis- and trans-ring fusions arising from common intermediates

Steven D Townsend¹, Audrey G Ross², Kai Liu¹

¹Laboratory of Bioorganic Chemistry, Sloan Kettering Institute for Cancer Research, New York, NY 10065; and.

Proceedings of the National Academy of Sciences of the United States of America

|May 21, 2014

Abstract:

Highly concise and stereospecific routes to cis and trans fusion, carrying various functionality at one of the bridgehead carbons, have been accomplished.

Keywords:

Diels–Alder cycloaddition angular methylation cyclobutenone mechanistic studies

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