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Updated: Apr 29, 2026
12:30
Synthesis of a Thiol Building Block for the Crystallization of a Semiconducting Gyroidal Metal-sulfur Framework
Published on: April 9, 2018
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Ligand-coupling assembly of Re(I)-thiolate complexes
Biing-Chiau Tzeng1, An Chao, Manas Banik
1Department of Chemistry and Biochemistry, National Chung Cheng University, 168 University Rd, Min-Hsiung, Chiayi 62102, Taiwan. chebct@ccu.edu.tw.
Dalton Transactions (Cambridge, England : 2003)
|May 23, 2014
Summary
This study synthesized novel rhenium(I) complexes using solvothermal reactions. Reaction conditions like temperature and solvent influenced the in situ ligand formation and complex structures.
Area of Science:
- Organometallic Chemistry
- Coordination Chemistry
- Materials Science
Background:
- Rhenium complexes are valuable in catalysis and materials science.
- Solvothermal synthesis offers control over complex formation.
- In situ ligand modification is key to tuning complex properties.
Purpose of the Study:
- To synthesize and structurally characterize new rhenium(I) complexes.
- To investigate the influence of reaction conditions on ligand formation.
- To compare the reactivity of 2-mercaptobenzothiazole (HNS2) and 2-mercaptobenzoxazole (HNOS).
Main Methods:
- Solvothermal reactions of Re2(CO)10 with HNS2 or HNOS.
- X-ray diffraction for structural characterization.
- Systematic variation of reaction solvents and temperatures.
Main Results:
- Synthesis of four rhenium(I) complexes (1-4) with in situ ligands.
- Reaction temperature and solvent significantly affected ligand formation in the HNS2 system.
- Complexes 2 and 4, derived from HNS2 and HNOS respectively, showed anti and syn conformations.
Conclusions:
- Reaction conditions are critical for controlling ligand synthesis and complex structures.
- HNS2 and HNOS exhibit distinct reactivity patterns under solvothermal conditions.
- The study provides insights into the formation of dinuclear rhenium complexes with varied conformations.
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