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Updated: Apr 29, 2026

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
Published on: April 19, 2019
N,N'-(Ethane-1,2-di-yl)di-benzene-carbo-thio-amide
Masayuki Nagasawa1, Yuji Sasanuma1, Hyuma Masu2
1Department of Applied Chemistry and Biotechnology, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan.
Abstract:
The title compound, C16H16N2S2, adopts a gauche (+)-gauche (+)-gauche (+) (g(+)g(+)g(+) ) conformation in the NH-CH2-CH2-NH bond sequence. In the crystal, mol-ecules are connected by pairs of N-H⋯S=C hydrogen bonds and C-H⋯π inter-actions, forming a tape structure along the c-axis direction.
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