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Updated: Apr 28, 2026
Author Spotlight: Magnetometric Characterization of Intermediates in the Solid-State Electrochemistry of Redox-Active Metal-Organic Frameworks
Published on: June 9, 2023
Fe3O4 nanosphere@microporous organic networks: enhanced anode performances in lithium ion batteries through
Byungho Lim1, Jaewon Jin, Jin Yoo
1Department of Chemistry and Department of Energy Science, Sungkyunkwan University, Suwon 440-746, Korea. sson@skku.edu.
Abstract:
Very thin microporous organic networks were formed on the surface of Fe3O4 nanospheres by Sonogashira coupling of tetra(4-ethynylphenyl)methane and 1,4-diiodobenzene. The thickness was controlled by screening the number of building blocks. Through carbonization, Fe3O4@C composites were prepared. The Fe3O4@C composites with 4-6 nm carbon thickness showed promising reversible discharge capacities of up to 807 mA h g(-1) and enhanced electrochemical stability.
