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Updated: Apr 28, 2026
![[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst](/_next/image?url=https%3A%2F%2Fcloudfront.jove.com%2FCDNSource%2Fteasers%2F59739.jpg&w=3840&q=50)
[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
Electrochemical reduction of dioxygen by copper complexes with pyridylalkylamine ligands dissolved in aqueous buffer
Masafumi Asahi1, Shin-ichi Yamazaki, Shinobu Itoh
1Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology, 1-8-31, Midorigaoka, Ikeda, Osaka 563-8577, Japan. m.asahi@aist.go.jp.
Abstract:
The Cu(II)/Cu(I) redox properties and electrochemical O2 reduction activity of a series of Cu(II)-complexes with pyridylalkylamine ligands were investigated in a neutral buffer solution. The relationship between Cu(II)/Cu(I) redox properties and O2 reduction activity was clearly demonstrated by voltammetric analyses.
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