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Designed for Molecular Recycling: A Lignin-Derived Semi-aromatic Biobased Polymer
Published on: November 30, 2020
Efficient removal of malachite green dye using biodegradable graft copolymer derived from amylopectin and
Amit Kumar Sarkar1, Aniruddha Pal1, Soumitra Ghorai1
1Polymer Chemistry Laboratory, Department of Applied Chemistry, Indian School of Mines, Dhanbad 826004, India.
Abstract:
This article reports on the application of a high performance biodegradable adsorbent based on amylopectin and poly(acrylic acid) (AP-g-PAA) for removal of toxic malachite green dye (MG) from aqueous solution. The graft copolymer has been synthesized and characterized using various techniques including FTIR, GPC, SEM and XRD analyses. Biodegradation study suggests that the co-polymer is biodegradable in nature. The adsorbent shows excellent potential (Qmax, 352.11 mg g(-1); 99.05% of MG has been removed within 30 min) for removal of MG from aqueous solution. It has been observed that point to zero charge (pzc) of graft copolymer plays significant role in adsorption efficacy. The adsorption kinetics and isotherm follow pseudo-second order and Langmuir isotherm models, respectively. Thermodynamics parameters suggest that the process of dye uptake is spontaneous. Finally desorption study shows excellent regeneration efficiency of adsorbent.

