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Elastocapillary deformations on partially-wetting substrates: rival contact-line models.

Joshua B Bostwick1, Michael Shearer, Karen E Daniels

  • 1Department of Engineering Science and Applied Mathematics, Northwestern University, Evanston, IL 60208, USA. joshua.bostwick@northwestern.edu.

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Theoretical models for partially-wetting liquids deforming elastic substrates are crucial. This study presents a general solution incorporating surface stress, essential for accurate predictions and eliminating inadequate contact-line models.

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Area of Science:

  • Physics
  • Materials Science
  • Fluid Dynamics

Background:

  • Partially-wetting liquids deform elastic substrates.
  • Wetting forces at the contact-line require theoretical models.
  • Surface stress from liquid/solid and solid/gas interfaces influences deformation.

Purpose of the Study:

  • Develop a general theoretical solution for elastic substrate deformation due to wetting forces.
  • Incorporate internal surface stress contributions.
  • Compare different contact-line models and experimental results.

Main Methods:

  • Construct a general solution using a displacement potential function.
  • Solve a non-standard boundary-value problem using dual integral equations.
  • Incorporate surface stress (liquid/solid Σls and solid/gas Σsg).

Main Results:

  • A general solution for elastic deformations caused by wetting forces was derived.
  • The model incorporates generalized solid surface tension (Σls ≠ Σsg).
  • Comparisons with experiments were performed to validate the model.

Conclusions:

  • The generalization of solid surface tension is essential for partial-wetting models.
  • The developed model accurately describes substrate deformation.
  • Specific contact-line models were systematically eliminated based on experimental comparisons.