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Published on: May 21, 2019
Photo-induced glycosylation using reusable organophotoacids
Ryosuke Iwata1, Kanjiro Uda, Daisuke Takahashi
1Department of Applied Chemistry, Faculty of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kohoku-ku, Yokohama 223-8522, Japan. toshima@applc.keio.ac.jp.
Abstract:
The glycosylation reactions of glycosyl trichloroacetimidates and several alcohols using an organophotoacid as an activator under photoirradiation proceeded smoothly to give the corresponding glycosides in high yields. The organophotoacid was recovered and reused without any loss of efficiency.
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