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Ligand-Mediated Nucleation and Growth of Palladium Metal Nanoparticles
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In situ formation of well-dispersed palladium nanoparticles immobilized in imidazolium-based organic ionic polymers
Huaixia Zhao1, Yangxin Wang, Ruihu Wang
1State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. ruihu@fjirsm.ac.cn.
Chemical Communications (Cambridge, England)
|August 5, 2014
Abstract:
A new strategy for in situ generation of well-dispersed palladium nanoparticles (NPs) immobilized in imidazolium-based organic ionic polymers was presented. Without extra addition of palladium species, the as-synthesized ionic polymers showed excellent catalytic activity and good reusability in the hydrogenation of nitroarenes.
