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Published on: December 1, 2023
Photophysical and electrochemical characterization of a helical viologen, N,N'-dimethyl-5,10-diaza[5]helicene
Xiaoping Zhang1, Edward L Clennan, Navamoney Arulsamy
1Department of Chemistry, University of Wyoming , Laramie, Wyoming 82071, United States.
Abstract:
The first helical viologen (4,4'-bipyridinium salt) has been prepared and characterized. Its reduction to the radical cation at -0.22 V vs SCE makes it the most easily reduced redox-active helicene known. It exhibits absorption at 397 nm for the S1 ← S0 transition, and it is luminescent allowing measurement of both its singlet (59.3 ± 0.1 kcal/mol) and triplet (54 ± 1 kcal/mol) energies. In contrast to neutral helicenes, it is not aromatic π-stacked in the crystal and has a shortest interdication distance of 4.977 Å. Its racemization barrier is calculated to be a sensitive function of its redox state.
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