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Researchers developed a new imaging technique to directly observe atomic motion during molecular changes. This method uses laser-induced electron scattering for ultrafast, bond-specific structural analysis with picometre resolution.

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Area of Science:

  • Ultrafast optical science
  • Physical chemistry
  • Molecular imaging

Background:

  • Directly monitoring atomic motion during molecular transformations at the atomic scale is a significant challenge.
  • Existing methods lack the required spatio-temporal resolution for transient structural determination.

Purpose of the Study:

  • To establish the foundation for a novel imaging method enabling direct observation of atomic motion.
  • To achieve atomic-scale spatio-temporal resolution for studying molecular transformations.
  • To enable bond-specific structural analysis with picometre precision.

Main Methods:

  • Developed fixed-angle broadband laser-induced electron scattering (LIBES).
  • Employed structural retrieval via one-dimensional Fourier transform of photoelectron energy distribution.
  • Utilized scattering of a broadband wave packet generated by strong-field tunnel ionization.

Main Results:

  • Demonstrated a method for structural retrieval with picometre spatial resolution and bond specificity.
  • Achieved inherent femtosecond temporal resolution.
  • Established the potential for time-resolved tomography of transient molecular structures.

Conclusions:

  • The proposed fixed-angle broadband LIBES technique provides a foundation for a new class of molecular imaging.
  • Combining the technique with molecular alignment offers a pathway for multi-dimensional transient structural determination.
  • This advancement opens new avenues for studying ultrafast chemical dynamics.