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Quantum dynamics study of H + DBr and D + HBr reaction
Ai Jie Zhang1, JianFeng Jia, Hai Shun Wu
1Key Laboratory of Magnetic Molecules, Magnetic information Materials Ministry of Education, School of Chemistry and Material Science, Shanxi Normal University, Linfen, 041004, China.
Abstract:
Time-dependent quantum wave packet calculations have been performed for the H + DBr and D + HBr reaction using the recent diabatic potential energy surfaces. Reaction probabilities, integral cross sections, and rate constants are obtained. The results show that the isotopic effects have an influence on the nonadiabatic effect which is generally inversely proportional to the atom mass. The calculated rate constants are in good overall agreement with experimental values, indicating that the ab initio surfaces are accurate to describe the isotopic effects.
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