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Separation of Aldehydes and Reactive Ketones from Mixtures Using a Bisulfite Extraction Protocol
Published on: April 2, 2018
Selective oxidations of activated alcohols in water at room temperature
B H Lipshutz1, M Hageman, J C Fennewald
1Department of Chemistry & Biochemistry, University of California, Santa Barbara, CA 93106, USA. lipshutz@chem.ucsb.edu.
Abstract:
Allylic and benzylic alcohols can be selectively oxidized to their corresponding aldehydes or ketones in water containing nanoreactors composed of the designer surfactant TPGS-750-M. The oxidation relies on catalytic amounts of CuBr, bpy, and TEMPO, with N-methyl-imidazole; air is the stoichiometric oxidant.
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