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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
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Surface confined heteroleptic copper(II)-polypyridyl complexes for photonuclease activity
Vikram Singh1, Prakash C Mondal, Anup Kumar
1Department of Chemistry, University of Delhi, Delhi-110 007, India.
Chemical Communications (Cambridge, England)
|August 19, 2014
Abstract:
Heteroleptic copper(II)-polypyridyl complexes with extended π-conjugated, aromatic terminal units were immobilized on glass/Si substrates to intercalate DNA and cleave it upon photoexposure. Photonuclease activity is shown to be high, well reproducible and non-destructible towards the assembled complexes.
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