Electrical impedance spectroscopy of microchannel-nanochannel interface devices
Jarrod Schiffbauer1, Sinwook Park1, Gilad Yossifon1
1Faculty of Mechanical Engineering, Micro- and Nanofluidics Laboratory, Technion-Israel Institute of Technology, Technion City 32000, Israel.
Abstract:
We report experimental verification of the depression of the slope in the Warburg branch of the electrochemical impedance spectrum using a fabricated microchannel-nanochannel device. This was previously theoretically predicted to occur with increasing dc bias voltage as a result of nanochannel electro-osmotic flow and provides an example of the influence of net fluid flow on electrokinetic transport. The dominant influence of nanochannel polarization in the kHz range of the impedance response is also demonstrated experimentally. This latter effect may be significant in both fundamental electrokinetics of micronanochannel devices as well as in practical molecular sensing applications.
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