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Updated: Apr 25, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

Published on: May 9, 2014

Silver particle monolayers — Formation, stability, applications.

Magdalena Oćwieja¹, Zbigniew Adamczyk¹, Maria Morga¹

¹Jerzy Haber Institute of Catalysis and Surface Chemistry, Polish Academy of Sciences, Niezapominajek 8, 30-239 Cracow, Poland.

Advances in Colloid and Interface Science

|August 30, 2014

Summary

This summary is machine-generated.

This review details silver nanoparticle monolayer formation on solid substrates. A hybrid model explains particle binding and release, highlighting discrete ion pair interactions over averaged zeta potential theories.

Keywords:

Applications of silver nanoparticles Chemical synthesis of silver particles Deposition of silver particles Modeling of silver particle deposition Release kinetics of silver particles Silver particle monolayers and bilayers

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Gold Nanoparticle Synthesis

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Published on: July 10, 2021

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Last Updated: Apr 25, 2026

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates

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Published on: May 9, 2014

Synthesis, Assembly, and Characterization of Monolayer Protected Gold Nanoparticle Films for Protein Monolayer Electrochemistry

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Published on: October 4, 2011

Gold Nanoparticle Synthesis

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Published on: July 10, 2021

Area of Science:

Materials Science
Surface Chemistry
Nanotechnology

Background:

Self-assembly processes are crucial for creating ordered structures.
Silver nanoparticles (AgNPs) offer unique properties for various applications.

Purpose of the Study:

To comprehensively review the formation of silver nanoparticle monolayers on solid substrates.
To critically evaluate synthesis and characterization methods for AgNP suspensions and their deposition kinetics.

Main Methods:

Discussion of silver nanoparticle synthesis routes, focusing on chemical reduction in aqueous media.
Review of bulk suspension characterization techniques and in situ methods for deposition/release kinetics (e.g., streaming potential).
Comparison of ex situ (AFM/SEM) and in situ (streaming potential) measurements for binding energy determination.

Main Results:

Experimental data illustrate key features of monolayer formation, influenced by concentration, size, ionic strength, temperature, and pH.
A hybrid theoretical approach combining bulk transport and random sequential adsorption models adequately interprets experimental results.
Particle release kinetics are governed by discrete electrostatic interactions among ion pairs, not mean-field zeta potential.

Conclusions:

The ion pair concept successfully explains the minor dependence of binding energy on various parameters.
The review demonstrates the equivalency of ex situ and in situ methods for binding energy determination.
Applications of silver nanoparticle monolayers in medicine, analytical chemistry, and catalysis are discussed.