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Updated: Apr 25, 2026

Revealing Dynamic Processes of Materials in Liquids Using Liquid Cell Transmission Electron Microscopy
Published on: December 20, 2012
In situ electron holographic study of Ionic liquid
Manabu Shirai1, Toshiaki Tanigaki2, Shinji Aizawa3
1Hitachi, Ltd., Central Research Laboratory, Hatoyama, Saitama 350-0395, Japan.
Abstract:
Investigation of the effect of electron irradiation on ionic liquid (IL) droplets using electron holography revealed that electron irradiation changed the electrostatic potential around the IL. The potential for low electron flux irradiation (0.5 × 10(17)e/m(2)s) was almost constant as a function of time (up to 180 min). For higher electron flux irradiation (2 × 10(17)e/m(2)s), the potential increased exponentially for a certain time, reflecting the charging effect and then leveled off. The IL was found to be changed from liquid to solid state after a significant increase in the electrostatic potential due to electron irradiation.

